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All simple
or compound colors, and all the shades of color which nature or art can
produce, and which might be thought proper for the different kinds of painting,
would form a very extensive catalogue, were we to take into consideration
only certain external characters, or the intensity of their tint. But art,
founded on the experience of several centuries, has prescribed bounds to
the consumption of coloring substances, and to the application of them
to particular purposes. To cause a substance to be admitted into the class
of coloring bodies employed by it is not sufficient for it to contain a
color; to brightness and splendor it must also unite durability in the
tint or color which it communicates.
To make Black
Paint.
Usage requires attention in the choice of the
matters destined for black. The following are their properties:
Black from peach-stones is dull.
Ivory-black is warm. strong and beautiful when it
has been well attenuated under the muller.
Black from the charcoal of beech-wood, ground
on porphyry, has a bluish tone.
Lampblack may be rendered mellower by making
it with black which has been kept an hour in a state of redness in a close
crucible. It then loses the fat matter which accompanies this kind of soot.
Black furnished by the charcoal of vine-twigs,
ground on porphyry, is weaker, and of a dirty gray color when coarse and
alone, but it becomes blacker the more the charcoal has been divided. It
then forms a black very much sought after, and which goes a great way.
To make Paints from Lampblack.
The consumption of lampblack is very extensive
in common painting, It serves to modify the brightness of the tones of
the other colors, or to facilitate the composition of secondary colors.
The oil paint applied to iron grates and railing, and the paint applied
to paper snuff-boxes, to those made of tin-plate, and to other articles
with dark grounds, consume a very large quantity of this black. Great solidity
may be given to works of this kind by covering them with several coatings
of the fat turpentine, or golden varnish, which has been mixed with lampblack,
washed in water, to separate the foreign bodies introduced into it by the
negligence of the workmen who prepare it.
After the varnish is applied the articles are
dried in a stove by exposing them to a heat somewhat greater than that
employed for articles of paper. Naples yellow, which enters into the composition
of black varnish, is the basis of the dark brown observed on tobacco-boxes
of plate-iron, because this color changes to brown when dried with the
varnish.
To make a Superior Lampblack.
Suspend over a lamp a funnel of tin plate having
above it a pipe to convey from the apartment the smoke which escapes from
the lamp. Large mushrooms, of a very black, carbonaceous matter, and exceedingly
light, will be formed at the summit of the cone. This carbonaceous part
is carried to such a state of division as cannot be given to any other
matter, by grinding it on a piece of porphyry.
This black goes a great way in every kind of
painting. It may be rendered drier by calcination in close vessels.
The funnel ought to be united to the pipe,
which conveys off the smoke, by means of wire, because solder would be
melted by the flame of the lamp.
To make Black from Ground Pitcoal.
The best for this purpose is that which has
a shining fracture. It affords, perhaps, the most useful brown the artist
can place on his palet, being remarkably clear, not so warm as Vandyke
brown, and serving as a shadow for blues, reds, or yellows, when glazed
over them. It seems almost certain that Titian made large use of this material.
Coal, when burnt to a white heat, then quenched in water, and ground down,
gives an excellent blue black. This belongs to artists' colors.
To make Black from Wine-lees.
This black results from the calcination of
wine-lees and tartar, and is manufactured on a large scale in some districts
of Germany, in the environs of Mentz, and even in France. This operation
is performed in large cylindric vessels, or in pots, having an aperture
in the cover to afford a passage to the smoke, and to the acid and alkaline
vapors which escape during the process. When no more smoke is observed,
the operation is finished. The remaining matter, which is merely a mixture
of salts and a carbonaceous part very much attenuated, is then washed several
times in boiling water, and it is reduced to the proper degree of fineness
by grinding it on porphyry.
If this black be extracted from dry lees, it
is coarser than that obtained from tartar, because the lees contain earthy
matters which are confounded with the carbonaceous part.
This black goes a great way, and has a velvety
appearance. It is used chiefly by copper-plate printers.
Another. - Peach-stones, burnt in a close vessel,,
produce a charcoal, which, when ground on porphyry, is employeed in painting
to give an old gray.
Another. - Vine twigs reduced to charcoal give
a bluish black, which goes a great way. When mixed with white it produces
a silver white which is not produced by other blacks; it has a pretty near
resemblance to the black of peach stones, but to bring this color to the
utmost degree of perfection, it must be carefully ground on porphyry.
To make Ivory and Boneblack.
Put into a crucible surrounded by burning coals,
fragments or turnings of ivory, or of the osseous parts of animals, and
cover it closely. The ivory or bones, by exposure to the heat, will be
reduced to charcoal. When no more smoke is seen to pass through the joining
of the cover, leave the crucible over the fire for half an hour or longer,
or until it has completely cooled. There will then be found in it a hard
carbonaceous matter, which, when pounded and ground on porphyry with water,
is washed on a filter with warm water and then dried. Before it is used
it must be again subjected to the matter.
Black furnished by bones is reddish. That produced
by ivory is more beautiful. It is brighter than black obtained from peach-stones.
When mixed in a proper dose with white oxide of lead, it forms a beautiful
pearl gray. Ivory-black is richer. The Cologne and Cassel-black are formed
from ivory.
Fine Black Color.
Take some camphor and set it on fire; from
the flame will arise a very dense smoke, which may be collected on a common
saucer by holding it over the flame. This black, mixed with gum arabic,
is far superior to most India-ink.
Miniature painters, who use colors in small
quantities, sometimes obtain a most beautiful and perfect black by using
the buttons which form on the snuff of a candle when allowed to burn undisturbed.
These are made to fall into a small thimble, or any other convenient vessel
which can be immediately covered with the thumb, to exclude the air. This
is found to be perfectly free from grease, and to possess every desirable
quality.
To make White
Paint.
To Paint in White Distemper.
Grind fine in water Bougival white, a kind
of marl or chalky clay, and mix it with size. It may be brightened by a
small quantity of indigo, or charcoal-black.
The White destined for varnish or oil requires
a metallic oxide, which gives more body to the color. Take ceruse, reduced
to powder, and grind it with oil of pinks and 1/4 oz. of sulphate of zinc
for each pound of oil. Apply the second coating without the sulphate of
zinc, and suffer it to dry. Cover the whole with a stratum of sandarach
varnish. This color is curable, brilliant and agreeable to the eye.
Boiled linseed oil might be employed instead
of oil of pinks, but the color of it would in some degree injure the purity
of the white.
Another. - White is prepared also with pure
white oxide of lead, ground with a little essence, added to oil of pinks
and mixed with gallipot varnish. The color may be mixed also with essence
diluted with oil, and without varnish, which is reserved for the two last
coatings. If for a lively white, the color is heightened with a little
Prussian blue or indigo, or with a little prepared black. The latter gives
it a gray cast. But pure white lead, the price of which is much higher
than ceruse, is reserved for valuable articles. In this particular case,
if a very fine durable white be required, grind it with a little essence,
and mix it with sandarach or varnish.
To Paint in Light Gray and Distemper.
Ceruse, mixed with a small quantity of lamp-black,
composes a gray, more or less charged, according to the quantity of black.
With this matter, therefore, mixed with black in different doses, a great
variety of shades may be formed, from the lightest to the darkest gray
If this color be destined for distemper, it
is mixed with water; if intended for oil painting, it is ground with nut-oil,
or oil of pinks, and with essence added to oil, if designed for varnish.
This color is durable and very pure, if mixed with camphorated mastic varnish;
the gallipot varnish renders it so solid that it can bear to be struck
with a hammer, if, after the first stratum it has been applied with varnish,
and without size. For the last coating sandarach varnish, and camphorated
varnish are proper; and for the darkest gray, spirituous sandarac varnish.
To make Flaxen
Gray.
Ceruse, or white lead, still predominates in
this color, which is treated as the other grays, but with this difference,
that it admits a mixture of lake instead of black. Take the quantity, therefore,
of cernse necessary, and grind it separately. Then mix it up, and add the
lake and Prussian blue, also ground separately. The quantities of the last
two colors ought to be proportioned to the tone of color required.
This color is proper for distemper, varnish,
and oil painting. For varnish, grind it with mastic gallipot varnish, to
which a little oil of pinks has been added, and then mix it up with common
gallipot varnish. For oil painting, grind with unprepared oil of pinks,
and mix up with resinous drying nut-oil. The painting is brilliant and
solid.
When the artist piques himself upon carefully
preparing those colors which have splendor, it will be proper, before he
commences his labor, to stop up the holes formed by the heads of the nails
in wainscoting with putty.
Every kind of sizing which, according to usual
custom, precedes the application of varnish, ought to be prescribed as
highly prejudicial, when the wainscoting consists of firwood. Sizing maybe
admitted for plaster, but without any mixture. A plain stratum of strong
glue and water spread over it, is sufficient to fill up the pores to prevent
any unnecessary consumption of the varnish.
The first stratum of color is ceruse without
any mixture, ground with essence added to a little oil of pinks, and mixed
up with essence. If any of the traces are uneven, rub it lightly, when
dry, with pumice-stone. This operation contributes greatly to the beauty
and elegance of the polish when the varnish is applied.
The second stratum is composed of ceruse changed
to flaxen gray by the mixture of a little Cologne earth, as much English
red or lake, and a particle of Prussian blue. First, so make the mixture
with a small quantity of ceruse, that the result shall be a smoky gray,
by the addition of the Cologne earth. The red, which is added, makes it
incline to fleshcolor, and the Prussian blue destroys the latter to form
a dark flaxen gray. The addition of ceruse brightens the tone. This stratum
and the next are ground, and mixed up with varnish as before.
This mixture of colors, which produces flaxen
gray, has the advantage over pearl gray, as it defends the ceruse from
the impression of the air and light, which makes it assume a yellowish
tint. Flaxen gray, composed in this manner, is unalterable. Besides, the
essence which forms the vehicle of the first stratum contributes to bring
forth a color, the tone of which decreases a little by the effect of drying.
This observation ought to serve as a guide to the artist, in regard to
the tint, which is always stronger in a liquid mixture than when the matter
composing it is extended in a thin stratum, or when it is dry.
To make Oak-wood
Color.
The basis of this color is still formed of
ceruse. Three-fourths of this oxide, and a fourth of ochre de rue, umber
earth, and yellow de Berri; the last three ingredients being employed in
proportions which lead to the required tint, give a spatter equally proper
for distemper, varnish, and oil.
To make Walnut-wood
Color.
A given quantity of ceruse, half that quantity
of ochre de rue, a little umber earth, red ochre, and yellow ochre de Berri;
compose this color proper for distemper, varnish, and oil.
For varnish, grind with a little drying nut-oil,
and mix up with the gallipot varnish.
For oil painting, grind with fat oil of pinks
added to drying oil or essence, and mix up with plain drying oil, or with
resinous drying oil.
To make Naples
and Montpellier Yellow.
The composition of these is simple, yellow
ochre mixed with ceruse, ground with water, if destined for distemper;
or drying nut-oil and essence, in equal parts, if intended for varnish;
and mixed up with camphorated mastic varnish; if for delicate objects,
or with gallipot varnish, give a very fine color the splendor of which
depends on the doses of the ceruse, which must be varied according to the
particular nature of the coloring matter employed. If the ground of the
color is furnished by ochre, and if oil painting be intended, the grinding
with oil added to essence may be omitted, as essence alone will be sufficient.
Oil, however, gives more pliability and more body.
To make Jonquil.
This is employed only in distemper. It may,
however, be used with varnish. A vegetable color serves as its base. It
is made with Dutch pink and ceruse, and ground with mastic gallipot varnish,
and mixed up with gallipot varnish.
To make Golden
Yellow Color.
Cases often occur when it is necessary to produce
a gold color without employing a metallic substance. A color capable of
forming an illusion is then given to the composition, the greater part
of which consists of yellow. This is accomplished by Naples or Montpellier
yellow, brightened by Spanish white, or by white of Morat, mixed with ochre
de Berri and realgar. The last substance, even in small quantity, gives
to the mixture a color imitating gold, and which may be employed in distemper,
varnish, or oil. When destined for oil, it is ground with drying or pure
nut-oil, added to essence or mixed with drying oil
To make Chamois
and Buff Color.
Yellow is the foundation of chamois color,
which is modified by a particle of minium, or what is better, cinnabar
and ceruse in small quantity. This color may be employed in distemper,
varnish, and oil. For varnish, it is ground with 1/2 common oil of pinks,
and 1/2 of mastic gallipot varnish. It is mixed with common gallipot varnish.
For oil painting, it is ground and mixed up with drying oil.
To make
Olive Color for Oil and Varnish.
Olive color is a composition the shades of
which may be diversified. Black and a little blue, mixed with yellow, will
produce an olive color. Yellow de Berri, or d'Auvergne, with a little verdigris
and charcoal, will also form this color.
It is ground and mixed up with mastic gallipot,
and common gallipot varnishes. For oil painting, it is ground with oil
added to essence, and mixed up with drying oil.
To make Olive Color for Distemper.
When intended for distemper, it will be necessary
to make a change in the composition. The yellow above-mentioned, indigo,
and ceruse, or Spanish white, are the new ingredients which must be employed.
To make Blue Colors.
Blue belongs to the order of vegetable substances,
like indigo, or to that of metallic substances, like Prussian blue; or
to that of stony mineral substances, as ultramarine; or to that of vitreous
substances colored by a metallic oxide, as Saxon blue. Ultramarine is more
particularly reserved for pictures. The same may, in some degree, be said
of Saxon blue.
When prussiate of iron or indigo is employed
without mixture, the color produced is too dark. It has no splendor, and
very often the light makes it appear black; it is. therefore, usual to
soften it with white.
To make Blue Distemper.
Grind with water as much ceruse as may be thought
necessary for the whole of the intended work; and afterwards mix it with
indigo, or Prussian blue.
This color produces very little effect in distemper,
it is not very favorable to the play of the light; but it soon acquires
brilliancy and splendor beneath the vitreous lamina of the varnish. Painting
in distemper, when carefully varnished, produces a fine effect.
To make Prussian Blue Paint.
The ceruse is ground with oil if for varnish,
made with essence, or merely with essence, which is equally proper for
oil painting; and a quantity of either of these blues sufficient to produce
the required tone is added.
For varnish, the ceruse is generally ground
with oil of pinks added to a little essence, and is mixed up with camphorated
mastic varnish, if the color is destined for delicate objects; or with
gallipot varnish if for wainscoting. This color, when ground and mixed
up with drying oil, produces a fine effect, if covered by a solid varnish
made with alcohol or essence.
If this oil color be destined for expensive
articles, such as valuable furniture subject to friction, it may be glazed
with the turpentine copal varnish.
Ultramarine.
A vitreous matter colored by oxide of cobalt
gives a tone of color different from that of the prussiate of iron and
indigo. It is employed for sky-blues. The case is the same with blue verditer,
a preparation made from oxide of copper and lime. Both these blues stand
well in distemper, in varnish, and in oil.
Saxon blue requires to be ground with drying
oil, and to be mixed with gallipot varnish. If intended for oil painting,
it is to be mixed up with resinous drying oil, which gives body to this
vitreous matter.
Blue Verditer
May be ground with pure alcoholic varnish added
to a little essence; and may be mixed up with compound mastic varnish if
the color is to be applied to delicate articles. Or mastic gallipot varnish,
added to a little drying oil, may be used for grinding, and common gallipot
varnish for mixing up, if the painting is intended for ceilings, wainscoting,
etc. This color is soft and dull, and requires a varnish to heighten the
tone of it, and give it play. Turpentine copal varnish is proper for this
purpose, if the article has need of a durable varnish.
To make Green
Color.
Every green color, simple or compound, when
mixed up with a white ground, becomes soft, and gives a sea-green of greater
or less strength, and more or less delicate, in the ratio of the respective
quantities of the principal colors. Thus, green oxides of copper, such
as chrome green, verdigris, dry crystallized acetate of copper, green composed
with blue verditer, and the Dutch pink of Troyes, or any other yellow,
will form, with a base of a white color, a seagreen, the intensity of which
may be easily changed or modified. The white ground for painting in distemper
is generally composed of Bougival white (white marl), or white of Troyes
(chalk), or Spanish white (pure clay); but for varnish or oil painting,
it is sought for in a metallic oxide. In this case, ceruse or pure white
oxide of lead is employed.
To make Sea-Green for Distemper.
Grind separately with water, mountain-green
and ceruse; and mix up with parchment size and water, adding ceruse in
sufficient quantity to produce the degree of intensity required in the
color. Watin recommends the use of Dutch pink of Troyes and white oxide
of lead, in proportions pointed out by experience; because the color thence
resulting is more durable.
In the case of a triple composition, begin
to make the green by mixing Dutch pink with blue verditer, and then lower
the color to sea-green, by the addition of ceruse ground with water.
To make Sea-Green for Varnish and Oils
Varnish requires that this color should possess
more body than it has in distemper, and this it acquires from the oil which
is mixed with it. This addition gives it even more splendor. Besides, a
green of a metallic nature is substituted for the green of the Dutch pink,
which is of a vegetable nature.
A certain quantity of verdigris, pounded and
sifted through a silk sieve, is ground separately with nut-oil, half drying
and half fat; and if the color is intended for metallic surfaces, it must
be diluted with camphorated mastic, or gallipot varnish.
On the other hand, the ceruse is ground with
essence, or with oils to which 1/2 of essence has been added, and the two
colors are mixed in proportions relative to the degree of intensity intended
to be given to the mixture. It may readily be conceived that the principal
part of this composition consists of ceruse.
If this color be destined for articles of a
certain value, crystallized verdigris, dried and pulverized, ought to be
substituted for common verdigris, and the painting must be covered with
a stratum of the transparent or turpentine copal varnish.
The sea-greens, which admit into their composition
metallic coloring parts, are durable and do not change.
The last compositions may be employed for sea-green
in oil painting, but it will be proper to brighten the tone a little more
than when varnish is used, because this color becomes darker by the addition
of yellow, which the oil developes in the course of time.
To make Bright
Red
A mixture of lake with vermilion gives that
beautiful bright red which painters employ for sanguine parts. This red
is sometimes imitated for varnishing small appendages of the toilette.
It ought to be ground with varnish and mixed up with the same, after which
it is glazed and polished. The mastic gallipot varnish is used for grinding;
gallipot varnish for mixing up, and camphorated mastic varnish for glazing.
To makeCrimson, or Rose-color
Crimson, or Rose-color.
Carminated lake - that which is composed of
alum charged with the coloring part of cochineal, ceruse, and carmine -
forms a beautiful crimson. It requires a particle of vermilion and of white
lead.
The use of this varnish is confined to valuable
articles.
To make Violet-color.
Violet is made indifferently with red and black,
or red and blue; and to render it more splendid, with red, white, and blue.
To compose violet therefore, applicable to varnish, take minium, or what
is still better, vermilion, and grind it with the camphorated mastic varnish
to which a fourth part of boiled oil and a little ceruse have been added,
then add a little Prussian blue ground in oil. The proportions requisite
for the degree of intensity to be given to the color will soon be found
by experience. The white brightens the tint. The vermilion and Prussian
blue, separated or mixed, give hard tones, which must be softened by an
intermediate substance that modifies, to their advantage, the reflections
of the light.
To make Chestnut-color.
This color is composed of red, yellow and black.
The English red, or red ochre of Auvergne, ochre de rue and a little black,
form a dark chestnut color. It is proper for painting of every kind. If
English red, which is dryer than that of Auvergne, be employed, it will
be proper, when the color is intended for varnish, to grind it with drying
nutoil. The ochre of Auvergne only be ground with the mastic gallipot,
and mixed up with gallipot varnish.
The most experienced artists grind dark colors
with linseed oil, when the situation will admit of its being used, because
it is more drying. For articles without doors nut-oil is preferable. The
colors of oak-wood, walnut-tree, chestnut, olive, and yellow, require the
addition of a little litharge ground on porphyry: it hastens the desiccation
of the color, and gives it body.
But if it is intended to cover these colors
with varnish, as is generally done in wainscoting, they must be mixed up
with essence, to which a little oil has been added. The color is then much
better dispersed to receive the varnish, under which it exhibits all the
splendor it can derive from the reflection of the light.
To make
a Dryer for Painting.
Vitreous oxide of lead (litharge), is of no
other use in painting than to free oils from their greasy particles, for
the purpose of communicating to them a drying quality. Red litharge, however,
ought to be preferred to the greenish yellow; it is not so hard, and answers
better for the purpose to which it is destined.
When painters wish to obtain a common color
of the ochrey kind, and have no boiled oil by them, they may paint with
linseed oil, not freed from its greasy particles, by mixing with the color
about 2 or 3 parts of litharge, ground on a piece of porphyry with water,
dried, and reduced to fine powder, for 16 parts of oil. The color has a
great deal of body, and dries as speedily as if mixed with drying oil.
Siccitive Oil.
Boil together for 2 hours on a slow and equal
fire, 1/2 oz. of litharge, as much calcined ceruse, and the same of terre
d'ombre and talc, with 1 lb. of linseed oil, carefully stirring the whole
time. It must be carefully skimmed and clarified. The older it grows the
better it is. A quarter of a pint of this dryer is required to every pound
of color.
To Paint
in Fresco.
It is performed with water-colors on fresh
plaster, or a wall laid with mortar not dry. This sort of painting has
a great advantage by its incorporating with the mortar, and drying along
with it becomes very durable.
The ancients painted on stucco, and we may
remark in Vitruvius what infinite care they took in making the plastering
of their buildings, to render them beautiful and lasting, though the modern
painters find a plaster of lime and sand preferable to it.
To Paint
Fire-Places and Hearths.
The Genevese employ a kind of stone, known
under the name of molasse, for constructing fire-places and stoves, after
the German manner. This stone is brought from Saura, a village of Savoy,
near Geneva. It has a grayish color, inclining to blue, which is very agreeable
to the eye. This tint is similar to that communicated to common whitewashing
with lime, chalk, or gypsum, the dullness of which is corrected by a particle
of blue extract of indigo, or by charcoal black.
To make Red
Distemper for Tiles.
Dip a brush in water from a common lye, or
in soapy water, or in water charged with a 20th part of the carbonate of
potash (pearlash), and draw it over the tiles. This washing thoroughly
cleanses them, and disposes all the parts of the pavement to receive the
distemper.
When dry, dissolve in 8 pts. of water 1/2 lb.
of Flanders glue; and while the mixture is boiling, add 2 lbs. of red ochre;
mix the whole with great care. Then apply a stratum of this mixture to
the pavement, and when dry apply a second stratum with drying linseed oil,
and a third with the same red mixed up with size. When the whole is dry,
rub it with wax.
To Distemper
in Badigeon.
Badigeon is employed for giving an uniform
tint to houses rendered brown by time, and to churches. Badigeon, in general,
has a yellow tint. That which succeeds best is composed of the saw-dust
or powder of the same kind of stone and slacked lime, mixed up in a bucket
of water holding in solution 1 lb. of the sulphate of alumina (alum). It
is applied with a brush.
At Paris, and in other parts of France, where
the large edifices are constructed of a soft kind of stone, which is yellow,
and sometimes white when it comes from the quarry, but which in time becomes
brown, a little ochre de rue is substituted for the powder of the stone
itself, and restores to the edifice its original tint.
To make a Composition
for rendering Canvas, Linen, and Cloth durable, Pliable, and Water-proof.
To make it Black.
First, the canvas, linen, or cloth is to be
washed with hot or cold water, the former preferable, so as to discharge
the stiffening which all new canvas, linen, or cloth contains; when the
stiffening is perfectly discharged, hang the canvas, linen, or cloth up
to dry; when perfectly so, it must be constantly rubbed by the hand until
it becomes supple; it must then be stretched in a hollow frame very tight,
and the following ingredients are to be laid on with a brush for the first
coat, viz.; 8 qts. of boiled linseed oil, 1/2 oz. of burnt umber, 1/4 oz.
of sugar of lead, 1/4 oz. of white vitriol, 1/4 oz. of white lead.
The above ingredients, except the white lead,
must be ground fine with a small quantity of the above-mentioned oil, on
a stone and muller; then mix all the ingredients up with the oil, and add
3 oz. of lampblack, which must be put over a slow fire in an iron broad
vessel, and kept stirred until the grease disappears. In consequence of
the canvas being washed and then rubbed, it will appear rough and nappy;
the following method must be taken with the second coat, viz. the same
ingredients as before, except the white lead; this coat will set in a few
hours, according to the weather; when set take a dry paint-brush and work
it very hard with the grain of the oanvas; this will cause the nap to lie
smooth.
The third and last coat makes a complete jet-black,
which continues its color: Take 3 galls. of boiled linseed oil, an ounce
of burnt umber, 1/2 oz. of sugar of lead, 1/4 oz. of white vitriol, 1 oz.
of Prussian blue, and 1/4 oz. of verdigris; this must be all ground very
fine in a small quantity of the above oil; then add 4 oz. of lampblack,
put through the same process of fire as the first coat. The above are to
be laid on and used at discretion, in a similar way to paint. To make lead
color, the same ingredients as before in making the black, with the addition
of white lead in proportion to the color you wish to have, light or dark.
To make it Green.
Yellow ochre, 4 oz.; Prussian blue, 3/4 oz.;
white lead, 3 oz.; white vitriol, 1/2 oz.; sugar of lead 1/4 oz.; good
boiled linseed oil sufficient to make it of a thin quality, so as to go
through the canvas.
To make it Yellow.
Yellow ochre, 4 oz.; burnt umber, 1/4 oz.;
white lead, 6 or 7 oz.; white vitriol, 1/4 oz.; sugar of lead, 1/4 oz.;
boiled linseed oil, as in green.
To make it Red.
Red lead, 4 oz.; vermilion 2 oz.; white vitriol
1/4 oz.; sugar of lead 1/4 oz.; boiled linseed oil as before.
To make it Gray.
Take white lead, a little Prussian blue, according
to the quality you want, which will turn it to a gray color; a proportion
of sugar of lead and white vitriol, as mentioned in the other colors, boiled
linseed oil sufficient to make it of a thin quality.
To make it White.
White lead, 4 lbs.; spirits of turpentine,
1/4 pt.; white vitriol, 1/2 oz.; sugar of lead, 1/2 oz.; boiled oil sufficient
to make it of a thin quality.
The above ingredients, of different colors,
are calculated as near as possible; but, as one article may be stronger
than another, which will soon be discovered in using, in that case the
person working the color may add a little, or diminish, as he may find
necessary.
The same preparation for wood or iron, only
reducing the oil about 3 qt. out of 8, and to be applied in the same manner
as paint or varnish, with a brush.
ARTISTS'
OIL COLORS.
On Coloring Materials.
The composition of colors as respects those
leading tests of excellence, preservation of general tints, and permanency
of brilliant hues, during their exposure for many centuries to the impairing
assaults of the atmosphere, is a preparation in which the ancient preparers
of these oily compounds, have very much excelled, in their skilfulness,
the moderns. It is a fact, that the ancient painted walls, to be seen at
Dendaras, although exposed for many ages to the open air, without any covering
or protection, still possess a perfect brilliancy of color, as vivid as
when painted, perhaps 2000 years ago. The Egyptians mixed their colors
with some gummy substance, and applied them detached from each other without
any blending or mixture. They appeared to have used six colors, viz., white,
black, blue, red, yellow, and green; they first covered the canvas entirely
with white, upon which they traced the design in black, leaving out the
lights of the ground color. They used minium for red, and generally of
a dark tinge. Pliny mentions some painted ceilings in his day in the town
of Ardea, which had been executed at a date prior to the foundation of
Rome. He expresses great surprise and admiration at their freshness, after
the lapse of so many centuries. These are, undoubtedly, evidences of the
excellence of the ancients in their art of preparing colors. In the number
of them there is, probably, not much difference between the ancient and
modern knowledge. The ancients seem to have been possessed of some colors
of which we are ignorant, while they were unacquainted, themselves, with
some of those more recently discovered. The improvements of chemistry have,
certainly, in later times, enriched painting with a profusion of tints,
to which, in point of brilliancy at least, no combination of primitive
colors known to the ancients could pretend; but the rapid fading in the
colors of some of the most esteemed masters of the Modern School, proves
at least there is something defective in their bases or mode of preparing
them. This fault is peculiarly evident in many of the productions from
our esteemed master, Sir Joshua Reynolds, which, although they have not
issued from his pallet more than 40 years, carry an impoverishment of surface,
from the premature fading of their colors, so as almost to lose, in many
instances, the identity of the subjects they represent. On this head (and
a most important one it is), the superiority of the ancient compounders
completely carries away the palm of merit.
To Prepare
Ultramarine.
Separate from the stone the most apparent parts
of the ultramarine, reduce them to the size of a pea, and, having brought
them to a red heat in a crucible, throw them in that state into the strongest
distilled vinegar. Then grind them with the vinegar, and reduce them to
an impalpable powder; next take of wax, red colophonium, and lapis lazuli,
an equal quantity, say 1/2 oz. of each of these three substances; melt
the wax and the colophonium in a proper vessel, and add the powder to the
melted matter, then pour the mass into cold water, and let it rest eight
days. Next take two glass vessels filled with water, as hot as the hand
can bear, knead the mass in the water, and when the purest part of the
ultramarine has been extracted remove the resinous mass into the other
vessels, where finish the kneading to separate the remainder; if the latter
portion appears to be much inferior, and paler than the former, let it
rest for 4 days, to facilitate the precipitation of the ultramarine, which
extract by decantation, and wash it in fair water.
Ultramarine of four qualities may be separated
by this process. The first separation gives the finest, and as the operation
is repeated, the beauty of the powder decreases.
Kinckel considers immersion in vinegar as the
essential part of the operation. It facilitates the division, and even
the solution of the zeolitic and earthy particles soluble in that acid.
Another Method.
Separate the blue parts, and reduce them, on
a piece of porphyry, to an impalpable powder, which besprinkle with linseed
oil, then make a paste with equal parts of yellow wax, pine resin, and
colophonium, say, 8 oz. of each; and add to this paste 1/2 oz. of linseed
oil, 2 oz. of oil of turpentine, and as much more mastic.
Then take 4 parts of this mixture, and 1 of
lapis lazuli, ground with oil on a piece of porphyry, mix the whole warm,
and suffer it to digest for a month, at the end of which knead the mixture
thoroughly in warm water, till the blue part separates from it, and at
the end of some days decant the liquor. This ultramarine is exceedingly
beautiful.
These two processes are nearly similar, if
we except the preliminary preparation of Kinckel, which consists in bringing
the lapis lazuli to a red heat and immersing it in vinegar. It may be readily
seen, by the judicious observations of Morgraff on the nature of this coloring
part, that this calcination may be hurtful to certain kinds of azure stone.
This preliminary operation, however, is a test which ascertains the purity
of the ultramarine.
To Extract the Remainder of Ultramarine.
As this matter is valuable, some portions of
ultramarine may be extracted from the paste which has been kneaded in water;
nothing is necessary but to mix it with four times its weight of linseed
oil, to pour the matter into a glass of conical form, and to expose the
vessel in the balneum maria of an alembic. The water of which must be kept
in a state of ebullition for several hours. The liquidity of the mixture
allows the ultramarine to separate itself, and the supernatant oil is decanted.
The same immersion of the coloring matter in oil is repeated, to separate
the resinous parts which still adhere to it; and the operation is finished
by boiling it in water to separate the oil. The deposit is ultramarine;
but it is inferior to that separated by the first washing.
To Ascertain whether Ultramarine be Adulterated.
As the price of ultramarine, which is already
very high, may become more so on account of the difficulty of obtaining
lapis lazuli, it is of great importance that painters should be able to
detect adulteration. Ultramarine is pure if, when brought to a red heat
in a crucible, it stands that trial without changing its color; as small
quantities only are subjected to this test, a comparison may be made, at
very little expense, with the part which has not been exposed to the fire.
If adulterated, it becomes blackish or paler.
This proof, however, may not always be conclusive.
When ultramarine of the lowest quality is mixed with azure, it exhibits
no more body than sand ground on porphyry would do; ultramarine treated
with oil assumes a brown tint.
Another Method.
Ultramarine is extracted from lapis lazuli,
or azure stone, a kind of heavy zeolite, which is so hard as to strike
fire with steel, to cut glass, and to be susceptible of a fine polish.
It is of a bright blue color, variegated with white or yellow veins, enriched
with small metallic glands, and even veins of a gold color, which are only
sulphurets of iron (martial pyrites); it breaks irregularly. The specimens
most esteemed are those charged with the greatest quantity of blue.
Several artists have exercised their ingenuity
on processes capable of extracting ultramarine in its greatest purity;
some, however, are contented with separating the uncolored portions of
the stone, reducing the colored part to an impalpable powder, and then
grinding it for a long time with oil of poppies. But it is certain that,
in consequence of this ineffectual method, the beauty of the color is injured
by parts which are foreign to it; and that it does not produce the whole
effect which ought to be expected from pure ultramarine.
It may be readily conceived that the eminent
qualities of ultramarine must have induced those first acquainted with
the processes proper for increasing the merit and value of it, to keep
them a profound secret. This was indeed the case; ultramarine was prepared
long before any account of the method of extracting and purifying it was
known.
Artificial Ultramarine.
Sulphur, 2 parts; dry carbonate of soda, 1
part. Put them into a Hessian crucible, cover it up, and apply heat until
the mass fuses, then sprinkle into it gradually a mixture of silicate of
soda and aluminate of soda (the first containing 72 parts of silica, the
second, 70 parts of alumina); lastly, calcine for 1 hour, and wash in pure
water.
To Prepare Cobalt Blue. - Bleu
de Thenard.
Having reduced the ore to powder, calcine it
in a reverberatory furnace, stirring it frequently. The chimney of the
furnace should have a strong draught, in order that the calcination may
be perfect, and the arsenical and sulphurous acid vapors may be carried
off. The calcination is to be continued until these vapors cease to be
disengaged, which is easily ascertained by collecting in a ladle a little
of the gas in the furnace; the presence or absence of the garlic odor determines
the fact. When calcined, boil the result slightly in an excess of weak
nitric acid, in a glass matrass, decant the supernatant liquor, and evaporate
the solution thus obtained, nearly to dryness, in a capsule of platina
or porcelain. This residuum is to be thrown into boiling water and filtered,
and a solution of the subphosphate of soda to be poured into the clear
liquor, which precipitates an insoluble phosphate of cobalt. After washing
it well on a filter, collect it while yet in a gelatinous form, and mix
it intimately, with eight times its weight of alumina, in the same state
- if properly done the paste will have a uniform tint, through its whole
mass. This mixture is now to be spread on smooth plates and put into a
stove; when dry and brittle, pound it in a mortar, enclosed in a covered
earthen crucible, and heat it to a cherry-red for half an hour. On opening
the crucible, if the operation has been carefully conducted, the beautiful
and desired product will be found. Care should be taken that the alumina
in the gelatinous form be precipitated from the alum by a sufficient excess
of ammonia, and that it is completely purified by washing with water filtered
through charcoal.
To make Artificial Saxon Blue.
Saxon blue may be successfully imitated by
mixing with a divided earth prussiate of iron at the moment of its formation
and precipitation.
Into a solution of 144 grs. of sulphate of
iron pour a solution of yellow prussiate of potash.
At the time of the formation of iron add, in
the same vessel, a solution of 2 oz. of alum, and pour in with it the solution
of potash, just sufficient to decompose the sulphate of alumina, for a
dose of alkali superabundant to the decomposition of that salt might alter
the prussiate of iron. It will, therefore, be much better to leave a little
alum, which may afterwards be carried off by washing
As soon as the alkaline liquor is added, the
alumina precipitated becomes exactly mixed with the prussiate of iron,
the intensity of which it lessens by bringing it to the tone of common
Saxon blue. The matter is then thrown on a filter, and, after being washed
in clean water, is dried. This substance is a kind of blue verditer, the
intensity of which may vary according to the greater or less quantity of
the sulphate of alumina decomposed. It may be used for painting in distemper.
To make Blue Verditer.
Dissolve the copper, cold, in nitric acid (aquafortis),
and produce a precipitation of it by means of quicklime, employed in such
doses that it will be absorbed by the acid, in order that the precipitate
may be pure oxide of copper, that is, without any mixture. When the liquor
has been decanted, wash the precipitate and spread it out on a piece of
linen cloth to drain. If a portion of this precipitate, which is green,
be placed on a grinding-stone, and if a little quicklime, in powder, be
added, the green color will be immediately changed into a beautiful blue.
The proportion of the lime added is from 7 to 10 parts in 100. When the
whole matter acquires the consistence of paste, desiccation soon takes
place.
Blue verditer is proper for distemper, and
for varnish, but it is not for oil painting, as the oil renders it very
dark. If used it ought to be brightened with a great deal of white.
Chrome Yellow.
To a solution of bichromate of potassa add
a solution of nitrate of lead as long as a precipitate falls. Wash and
dry it.
Cadmium Yellow
Is a compound of cadmium and sulphur. It is
obtained by precipitation from a salt of cadmium by a current of sulphuretted
hydrogen gas, or by an alkaline sulphide.
Lemon Yellow (Steinbuhl Yellow)
Is a chromate of baryta, made by mixing hot
saturated solutions of bichromate of potassa and nitrate of baryta. Wash
and dry the precipitates. It is considered superior to chrome yellow.
To make Naples
Yellow.
Twelve oz. of ceruse, 2 oz. of the sulphuret
of antimony, 1/2 oz. of calcined alum, 1 oz. of sal ammoniac. Pulverize
these ingredients, and having mixed them thoroughly, put them into a capsule
or crucible of earth, and place over it a covering of the same substance.
Expose it at first to a gentle heat, which must be gradually increased
till the capsule is moderately red. The oxidation arising from this process
requires, at least, 5 hours' exposure to heat before it is completed. The
result of this calcination is Naples yellow, which is ground in water on
a porphyry slab with an ivory spatula, as iron alters the color. The paste
is then dried and preserved for use. It is a yellow oxide of lead and antimony.
There is no necessity of adhering so strictly
to the doses as to prevent their being varied. If a golden color be required
in the yellow, the proportions of the sulphuret of antimony and muriate
of ammonia must be increased. In like manner, if you wish it to be more
fusible, increase the quantities of sulphuret of antimony and calcined
sulphate of alumina.
To make Montpellier
Yellow.
Take 4 lbs. of litharge, well sifted, divide
it into 4 equal portions, and put it into as many glazed earthen vessels.
Dissolve also 1 lb. of sea-salt in about 4 lbs. of water. Pour a fourth
part of this solution into each of the 4 earthen vessels, to form a light
paste; let the whole rest for some hours, and when the surface begins to
grow white stir the mass with a strong wooden spatula. Without this motion
it would acquire too great hardness, and a part of the suit would escape
decomposition. As the consistence increases dilute the matter with a new
quantity of the solution, and if this is not sufficient recourse must be
had to simple water to maintain the same consistence. The paste will then
be very white, and in the course of 24 hours becomes uniform and free from
lumps; let it remain for the same space of time, but stir it at intervals
to complete the decomposition of the salt. The paste is then well washed,
to carry off the caustic soda (soda deprived of carbonic acid) which adheres
to it: the mass is put into strong linen cloth and subjected to a press.
The remaining paste is distributed in flat vessels, and these vessels are
exposed to heat, in order to effect a proper oxidation (calcination), which
converts it into a solid, yellow, brilliant matter, sometimes crystallized
in transverse striae.
This is Montpellier yellow, which may be applied
to the same purposes as Naples yellow.
To prepare Carmine.
This kind of fecula, so fertile in gradation
of tone by the effect of mixtures, and so grateful to the eye in all its
shades, so useful to the painter, and so agreeable to the delicate beauty,
is only the coloring part of a kind of dried insect known under the name
of cochineal.
A mixture of 36 grs. of chosen seed, 18 grs.
of autour bark, and as much alum thrown into a decoction of 5 grs. of pulverized
cochineal, and 5 lbs. of water, gives, at the end of from 5 to 10 days,
a red fecula, which, when dried, weighs from 40 to 48 grs. This fecula
is carmine. The remaining decoction, which is still highly colored, is
reserved for the preparation of carminated lakes.
Superfine
Carmine of Amsterdam.
Heat 6 buckets of rain-water, and when it commences
to boil throw in 2 lbs. of finely-powdered cochineal; continue boiling
2 hours, and then add 3 oz. of pure water, and immediately afterwards 4
oz. of binoxalate of potash. Boil again 1 minute, then remove the vessel
from the fire, and let the decoction stand 4 hours. Draw off the supernatant
liquid with a syphon into numerous basins, and put them aside upon a shelf
for about 3 weeks, at the end of which time a mouldy pellicle will be formed,
which is to be carefully removed with a whalebone, or by means of a small
sponge attached to the end of a stick. The water is then run off through
a syphon, which must reach to the bottom of the pans, the carmine being
so compact that it adheres. This carmine is dried in the shade, and is
of an intensely brilliant hue.
To prepare
Dutch Pink from Woad.
Boil the stems of woad in alum-water, and then
mix the liquor with clay, marl or chalk, which will become charged with
the color of the decoction. When the earthy matter has acquired consistence,
form it into small cakes and expose them to dry. It is under this form
that the Dutch pinks are sold in the color shops.
Dutch
Pink from Yellow Berries
The small blackthorn produces a fruit which
when collected green, is called yellow berries. These seeds, when boiled
in alum-water, form a Dutch pink superior to the former. A certain quantity
of clay or marl, is mixed with the decoction, by which means the coloring
part of the berries unites with the earthy matter and communicates to it
a beautiful yellow color.
Brownish
Yellow Dutch Pink.
Boil for an hour in 12 lbs. of water 1 lb.
of yellow berries, 1/2 lb. of the shavings of the wood of the Barberry
shrub and 1 lb. of wood-ashes. The decoction is strained through a piece
of linen cloth. Pour into this mixture, warm, and at different times, a
solution of 2 lbs. of the sulphate of alumina in 5 lbs. of water; a slight
effervescence will take place, and the sulphate being decomposed, the alumina
which is precipitated will seize on the coloring part. The liquor must
then be filtered through a piece of close linen, and the paste which remains
on the cloth,
when divided into square pieces, is exposed on boards to
dry. This is brown Dutch pink, because the clay in it is pure. The intensity
of the color shows the quality of the pink, which is superior to that of
the other compositions.
Dutch
Pink for Oil Painting.
By substituting for clay a substance which
prevents a mixture of that earth and metallic oxide, the result will be
Dutch pink of a very superior kind.
Boil separately 1 lb. of yellow-berries and
3 oz. of the sulphate of alumina in 12 lbs. of water, which must be reduced
to 4 lbs. Strain the decoction through a piece of linen, and squeeze it
strongly. Then mix up with it 2 lbs. of ceruse, finely ground on porphyry,
and 1 lb. of pulverized Spanish white. Evaporate the mixture till the mass
acquires the consistence of a paste; and, having formed it into small cakes,
dry them in the shade.
When these cakes are dry, reduce them to powder,
and mix them with a new decoction of yellow-berries. By repeating this
process a third time a brown Dutch pink will be obtained.
In general the decoctions must be warm when
mixed with the earth. They ought not to be long kept, as their color is
speedily altered by the fermentation. Care must be taken also to use a
wooden spatula for stirring the mixture.
When only one decoction of wood or yellow berries
is employed to color a given quantity of earth, the Dutch pink resulting
from it is of a bright-yellow color, and is easily mixed for use. When
the coloring part of several decoctions is absorbed the composition becomes
brown, and is mixed with more difficulty, especially if the paste be argillaceous;
for it is the property of this earth to unite with oily and resinous parts,
adhere strongly to them, and incorporate with them. In the latter case
the artist must not be satisfied with mixing the color; it ought to be
ground, an operation equally proper for every kind of Dutch pink, and even
the softest, when destined for oil painting.
To make Lake
from Brazil-wood.
Boil 4 oz. of the raspings of Brazil-wood in
15 pts. of pure water till the liquor is reduced to 2 pts. It will be of
a dark-red color, inclining to violet, but the addition of 4 or 5 oz. of
alum will give it a hue inclining to rosecolor. When the liquor has been
strained through a piece of linen cloth, if 4 oz. of the carbonate of soda
be added with caution, on account of the effervescence which takes place,
the color, which by this addition is deprived of its mordant, will resume
its former tint, and deposit a lake, which, when washed and properly dried,
has an exceedingly rich and mellow violet red color.
Another. - If only one-half of the dose of
mineral alkali be employed for this precipitation, the tint of the lake
becomes clearer, because the bath still retains the undecomposed aluminous
mordant.
Another. - If the method employed for Dutch
pinks be followed by mixing the aluminous decoction of Brazil-wood with
pure clay, such as Spanish white and white of Morat, and if the mixture
be deposited on a filter to receive the necessary washing, a lake of a
very bright dark rose-color will be obtained from the driers.
Lakes from other Coloring Substances.
By the same process a very beautiful lake may
be extracted from a decoction of logwood. In general, lakes of all colors,
and of all the shades of these colors, may be extracted from the substances
which give up their coloring part to boiling water, because it is afterwards
communicated by decomposition to the alumina precipitated from sulphate
of alumina, by means of an alkali, or the tincture may be mixed with a
pure and exceedingly white argillaceous substance, such as real Spanish
white, or white of Morat.
To prepare Rouge.
Carmine united to talc, in different proportions,
forms rouge employed for the toilette. Talc is distinguished also by the
name of Briancon chalk. It is a substance composed in a great measure of
clay, combined naturally with silex.
Carmine, as well as carminated lakes, the coloring
part of which is borrowed from cochineal, is the most esteemed of all the
compositions of this kind, because their coloring part maintains itself
without degradation. There are even cases where the addition of caustic
ammonia, which alters so many coloring matters, is employed to heighten
its color. It is for this purpose that those who color prints employ it.
Pink Saucers
Are made with extract of safflower (carthamus),
obtained by digesting it, after washing with cold water, in a solution
of carbonate of soda, and precipitating by citric acid. It dyes silk and
wool without a mordant. The extract is evaporated upon saucers as a dye-stuff,
and, mixed with powdered talc, forms a variety of rouge.
Carminated
Lake from Madder.
Boil 1 part of madder in from 12 to 15 pints
of water, and continue the ebullition till it be reduced to about 2 lbs.
Then strain the decoction through a piece of strong linen cloth, which
must be well squeezed; and add to the decoction 4 oz. of alum. The tint
will be a beautiful brightred, which the matter will retain if it be mixed
with proper clay. In this case, expose the thick liquor which is thus produced
on a linen filter, and subject it to one washing, to remove the alum. The
lake, when taken from the driers, will retain this bright primitive color
given by the alum.
Another Method.
If, in the process for making this lake, decomposition
be employed, by mixing with the bath an alkaline liquor, the alum, which
is decomposed, deprives the bath of its mordant, and the lake, obtained
after the subsequent washings, appears of the color of the madder bath,
without any addition: it is of a reddish brown. In this operation 7 or
8 oz. of alum ought to be employed for each pound of madder.
This kind of lake is exceedingly fine, but
a brighter red color may be given to it, by mixing the washed precipitate
with alum-water, before drying.
Improvement on the above.
If the aluminated madder bath be sharpened
with acetate of lead, or with arseniate of potash, the operator still obtains,
by the addition of carbonate of soda, a rosecolored lake of greater or
less strength
To make Dark-Red.
Dragon's blood, infused warm in varnish, gives
reds, more or less dark, according to the quantity of the coloring resin
which combines with the varnish. The artist, therefore, has it in his power
to vary the tones at pleasure.
Though cochineal, in a state of division, gives
to essence very little color in comparison with that which it communicates
to water, carmine may be introduced into the composition of varnish colored
by dragon's blood. The result will be a purple red, from which various
shades may be easily formed.
To Prepare
Violet.
A mixture of carminated varnish and dragon's
blood, added to that colored by prussiate of iron, produces violet.
To make a Fine
Red Lake.
Boil stick-lac in water, filter the decoction,
and evaporate the clear liquor to dryness over a gentle fire. The occasion
of this easy separation is, that the beautiful red color here separated
adheres only slightly to the outsides of the sticks broken off the trees
along with the gum-lac, and readily communicates itself to boiling water.
Some of this sticking matter also adhering to the gum itself, it is proper
to boil the whole together; for the gum does not at all prejudice the color,
nor dissolve in boiling water; so that after this operation the gum is
as fit for making sealing-wax as before, and for all other uses which do
not require its color.
To make a Beautiful
Red Lake.
Take any quantity of cochineal, on which pour
twice its weight of alcohol, and as much distilled water. Infuse for some
days near a gentle fire, and then filter. To the filtered liquor add a
few drops of the solution of tin, and a fine red precipitate will be formed.
Continue to add a little solution of tin every 2 hours, till the whole
of the coloring matter is precipitated. Lastly, edulcorate the precipitate
by washing it in a large quantity of distilled water and then dry it.
To Prepare Florentine
Lake.
The sediment of cochineal that remains in the
bottom of the kettle in which carmine is made, may be boiled with about
4 qts. of water, and the red liquor left after the preparation of the carmine
mixed with it, and the whole precipitated with the solution of tin. The
red precipitate must be frequently washed over with water. Exclusively
of this, 2 oz. of fresh cochineal, and 1 of crystals of tartar, are to
be boiled with a sufficient quantity of water, poured off clear, and precipitated
with the solution of tin, and the precipitate washed. At the same time
2 lbs. of alum are also to be dissolved in water, precipitated with a lixivium
of potash, and the white earth repeatedly washed with boiling water. Finally,
both precipitates are to be mixed together in their liquid state, put upon
a filter and dried. For the preparation of a cheaper sort, instead of cochineal,
1 lb. of Brazil wood may be employed in the preceding manner.
To make a Lake
from Madder.
Inclose 2 oz. troy of the finest Dutch madder
in a bag of fine and strong calico, large enough to hold three or four
times as much. Put it into a large marble or porcelain mortar, and pour
on it a pint of clear soft water cold. Press the bag in every direction,
and pound and rub it about with a pestle, as much as can be done without
tearing it, and when the water is loaded with color pour it off. Repeat
this process till the water comes off but slightly tinged, for which about
5 pts. will be sufficient. Heat all the liquor in an earthen or silver
vessel till it is near boiling, and then pour it into a large basin, into
which 1 oz. of alum, dissolved in 1 pt. of boiling soft water, has been
previously put: stir the mixture together, and while stirring pour in gently
about 1 1/2 oz. of a saturated solution of subcarbonate of potash; let
it stand till cold to settle; pour off the clear yellow liquor; add to
the precipitate a quart of boiling soft water, stirring it well; and when
cold separate by filtration the lake, which should weigh an oz. Fresh madder-root
is superior to the dry.
To give Various Tones to Lake.
A beautiful tone of violet, red, and even of
purplered, may be communicated to the coloring part of cochineal by adding
to the colored bath a solution of chloride of tin.
Another. - The addition of arseniate of potash
(neutral arsenical salt), gives shades which would be sought for in vain
with sulphate of alumina (alum).
To make a Carminated Lake by Extracting the
Coloring Part from Scarlet Cloth.
To prepare a carminated lake without employing
cochineal in a direct manner, by extracting the coloring matter from any
substance impregnated with it, such as the shearings of scarlet cloth.
Put into a kettle 1 lb. of fine wood-ashes
with 40 lbs. of water, and subject the water to ebullition for 1/4 of an
hour; then filter the solution through a piece of linen cloth till the
liquor passes through clear.
Place it on the fire; and having brought it
to a state of ebullition, add 2 lbs. of the shearings or shreds of scarlet
cloth, dyed with cochineal, which must be boiled till they become white,
then filter the liquor again, and press the shreds to squeeze out all the
coloring part.
Put the filtered liquor into a clean kettle,
and place it over the fire. When it boils pour in a solution of 10 or 12
oz. of alum in 2 lbs. of filtered spring-water. Stir the whole with a wooden
spatula till the froth that is formed is dissipated, and having mixed with
it 2 lbs. of a strong decoction of Brazil-wood, pour it upon a filter.
Afterwards wash the sediment with spring-water, and remove the cloth filter
charged with it to plaster dryers or to a bed of dry bricks. The result
of this operation will be a beautiful lake, but it has not the soft velvety
appearance of that obtained by the first method. Besides, the coloring
part of the Brazil-wood which unites to that of the cochineal in the shreds
of scarlet cloth, lessens in a relative proportion the unalterability of
the coloring part of the cochineal. For this reason purified potash ought
to be substituted for the wood-ashes.
To make a Red
Lake.
Dissolve 1 lb. of the best pearlash in 2 qts.
of water, and filter the liquor through paper; next add 2 more qts. of
water and 1 lb. of clean scarlet shreds, boil them in a pewter boiler till
the shreds have lost their scarlet color; take out the shreds and press
them, and put the colored water yielded by them to the other. In the same
solution boil another lb. of the shreds, proceeding in the same manner;
and likewise a third and fourth pound. Whilst this is doing, dissolve 1
1/2 lbs. of cuttle-fish bone in 1 lb. of strong aquafortis in a glass receiver,
add more of the bone if it appears to produce any ebullition in the aquafortis,
and pour this strained solution gradually into the other; but if any ebullition
be occasioned, more of the cuttle-fish bone must be dissolved as before,
and added till no ebullition appears in the mixture. The crimson sediment
deposited by this liquor is the lake: pour off the water, and stir the
lake in 2 galls. of hard spring-water, and mix the sediment in 2 galls.
of fresh water; let this method be repeated 4 or 5 times. If no hard water
can be procured, or the lake appears too purple, 1/2 an oz. of alum should
be added to each quantity of water before it is used. Having thus sufficiently
freed the latter from the salts, drain off the water through a filter,
covered with a worn linen cloth. When it has been drained to a proper dryness,
let it be dropped through a proper funnel on clean boards, and the drops
will become small cones or pyramids, in which form the lake must be dried
and the preparation is completed.
Another Method.
Boil 2 oz. of cochineal in 1 pt. of water,
filter the solution through paper, and add 2 oz. of pearlash dissolved
in 1/2 pint of warm water and filtered through paper. Make a solution of
cuttlebone, as in the former process, and to 1 pt. of it add 2 oz. of alum
dissolved in 1/2 pt. of water. Put this mixture gradually to the cochineal
and pearlash as long as any ebullition arises, and proceed as above.
A beautiful lake may be prepared from Brazil
wood, by boiling 3 lbs. of it for an hour in a solution of 3 lbs. of common
salt in 3 galls. of water and filtering the hot fluid through paper; add
to this a solution of 5 lbs. of alum in 3 galls. of water. Dissolve 3 lbs.
of the best pearlash in 1 1/2 galls. of water, and purify it by filtering;
put this gradually to the other till the whole of the color appears to
be precipitated and the fluid is left clear and colorless. But if any appearance
of purple be seen, add a fresh quantity of the solution of alum by degrees,
till a scarlet hue is produced. Then pursue the directions given in the
first process with regard to the sediment. If 1/2 lb. of seed-lac be added
to the solution of pearlash, and dissolved in it before its purification
by the filter and 2 lbs. of the wood and a proportional quantity of common
salt and water be used in the colored solution, a lake will be produced
that will stand well in oil or water; but it is not so transparent in oil
as without the seed-lac. The lake with Brazil wood may be also made by
adding 3 oz. of anatto to each pound of the wood, but the anatto must be
dissolved in the solution of pearlash.
After the operation, the dryers of plaster,
or the bricks which have extracted the moisture from the precipitate, are
exposed to the sun, that they may be fitted for another operation.
To make Prussian
Blue.
Dissolve sulphate of iron (copperas, green
vitriol) in water; boil the solution. Add nitric acid until red fumes cease
to come off, and enough sulphuric acid to render the liquor clear. This
is the persulphate of iron. To this add a solution of ferrocyanide of potassium
(yellow prussiate of potash), as long as any precipitate is produced. Wash
this precipitate thoroughly with water acidulated with sulphuric acid,
and dry in a warm place.
Soluble Prussian Blue.
Add ferrocyanide of potassium to a solution
freshly made of green vitriol in water. The white precipitate which falls,
becomes blue on exposure to the air, and is soluble in water.
Chrome Red.
Melt saltpetre in a crucible heated to dull
redness, and throw in gradually chrome yellow until no more red fumes arise.
Allow the mixture to settle, pour off the liquid portion, and wash rapidly
the sediment. The liquid portion contains chromate of potash, and may be
used to make chrome yellow.
To make Blue.
A diluted solution of sulphate of indigo.
To make Pink.
Cochineal boiled with bitartrate of potash
and sulphate alumina, or a decoction of Brazil-wood with sulphate alumina;
the color may be varied by the addition of carbonate potash.
To make Purple
A decoction of Brazil-wood and logwood affords,
with carbonate of potash, a permanent purple.
To make Orange
Lake.
Boil 4 oz. of the best anatto and 1 lb. of
pearlash, 1/2 an hour, in 1 gall. of water, and strain the solution through
paper. Mix gradually with this 1 1/2 lbs. of alum, in another gallon of
water, desisting when no ebullition attends the commixture. Treat the sediment
in the manner already directed for other kinds of lake, and dry it in square
bits or lozenges.
To make a Yellow
Lake.
Take 1 lb. of turmeric-root, in fine powder,
3 pt. of water, and 1 oz. of salt of tartar; put all into a glazed earthen
vessel, and boil them together over a clear gentle fire, till the water
appears highly impregnated and stains a paper to a beautiful yellow. Filter
this liquor, and gradually add to it a strong solution of alum, in water,
till the yellow matter is all curdled and precipitated. After this, pour
the whole into a filter of paper and the water will run off, and leave
the yellow matter behind. Wash it with fresh water till the water comes
off insipid, and then is obtained the beautiful yellow called lacque of
turmeric.
In this manner make a lake of any of the substances
that are of a strong texture, as madder, logwood, etc., but it will not
succeed in the more tender species, as the flowers of roses, violets, etc.,
as it destroys the nice arrangement of parts in those subjects on which
the color depends.
To make another Yellow Lake.
Make a lye of potash and lime sufficiently
strong; in this boil, gently, fresh broom-flowers till they are white,
then take out the flowers, and put the lye to boil in earthen vessels over
the fire; add as much alum as the liquor will dissolve, then empty this
lye into a vessel of clean water, and it will give a yellow color at the
bottom. Settle, and decant off the clear liquor. Wash this powder which
is found at the bottom, with more water till all the salts of the lye are
washed off; then separate the yellow matter, and dry it in the shade.
To Make a Yellow.
Gum guttae and terra merita give very beautiful
yellows, and readily communicate their color to copal varnish made with
turpentine. Aloes give a varied and orange tint.
Chloride of lead tinges vitreous matters of
a yellow color. Hence the beautiful glazing given to Queen's ware. It is
composed of 80 lbs. of chloride of lead, and 20 lbs. of flints ground together
very fine, and mixed with water till the whole becomes as thick as cream.
The vessels to be glazed are dipped in the glaze and suffered to dry.
To make Chinese
Yellow.
The acacia, an Egyptian thorn, is a species
of mimosa, from which the Chinese make that yellow which bears washing
in their silks and stuffs, and appears with so much elegance in their painting
on paper. The flowers are gathered before they are fully opened, and put
into an earthen vessel over a gentle heat, being stirred continually until
they are nearly dry, and of a yellow color: then to 1/2 lb. of the flowers
a sufficient quantity of rain-water is added, to hold the flowers incorporated
together. It is then to be boiled until it becomes thick, when it must
be strained. To the liquor is added 1/2 oz. of common alum, and 1 oz. of
calcined oystershells, reduced to a fine powder.
All these are mixed together into a mass. An
addition of a proportion of the ripe seeds to the flowers renders the colors
somewhat deeper. For making the deepest yellow add a small quantity of
Brazil-wood.
Tunic White,
Largely used as a substitute for white lead,
may be made by burning zinc, or by precipitating from a solution by caustic
alkali. It is the oxide of the metal, and is not blackened by sulphuretted
hydrogen.
To make a Pearl
White.
Pour some distilled water into a solution of
nitrate of bismuth as long as precipitation takes place, filter the solution,
and wash the precipitate with distilled water as it lies on the filter.
When properly dried, by a gentle heat, this powder is what is generally
termed pearl white.
Chrome Green.
Mix bichromate of potash with half its weight
of muriate of ammonia; heat the mixture to redness, and wash the mass with
plenty of boiling water. Dry the residue thoroughly. It is a sesquioxide
of chromium, and is the basis of the green ink used in bank-note printing.
Another. - Mix chrome yellow and Prussian blue.
Guignet's
Chrome Green.
Mix 3 parts of boracic acid and 1 part of bichromate
of potassa, heat to about redness. Oxygen gas and water are given off.
The resulting salt when thrown into water is decomposed. The precipitate
is collected and washed. This is a remarkably fine color, solid and brilliant
even by artificial light.
To make Scheele's
Green.
Dissolve 2 lbs. of blue vitriol in 6 lbs. of
water in a copper vessel, and in another vessel dissolve 2 lbs. of dry
white potash, and 11 oz. of white arsenic in 2 lbs. of water. When the
solutions are perfect pour the arsenical lye into the other gradually,
and about 1 lb. 6 oz. of good green precipitate will be obtained.
To make Green.
The acetic copper (verdigris) dissolved in
acetic acid, forms an elegant green.
Brunswick Green.
This is obtained from the solution of a precipitate
of copper in tartar and water, which, by evaporation, yields a transparent
cupreous tartar which is similar to the superfine Brunswick green.
Schweinfurth
or Emerald Green Color.
Dissolve in a small quantity of hot water,
6 parts of sulphate of copper; in another part, boil 6 parts of oxide of
arsenic with 8 parts of potash, until it throws out no more carbonic acid;
mix by degrees this hot solution with the first, agitating continually
until the effervescence has entirely ceased; these then form a precipitate
of a dirty greenish yellow, very abundant; add to it about 3 parts of acetic
acid, or such a quantity that there may be a slight excess perceptible
to the smell after the mixture; by degrees the precipitate diminishes the
bulk, and in a few hours there deposes spontaneously at the bottom of the
liquor entirely discolored, a powder of a contexture slightly crystalline,
and of a very beautiful green; afterwards the floating liquor is separated.
Green
Colors free from Arsenic.
Some green colors free from the objections
which apply to the arsenical greens, are described by Wiener. The first,
called "Elsner Green," is made by adding to a solution of sulphate of copper
a docoction of fustic, previously clarified by a solution of gelatine;
to this mixture is then added 10 or 11 per cent. of protochloride of tin,
and lastly an excess of caustic potash soda. The precipitate is then washed
and dried, whereupon it assumes a green color, with a tint of blue.
The "Tin-copper Green" is a stannate of copper,
and possesses a color which Gentele states is not inferior to any of the
greens free from arsenic. The cheapest way of making this is to heap 59
parts of tin in a Hessian crucible, with 100 parts of nitrate of soda,
and dissolve the mass, when cold, in a caustic alkali. When clear, this
solution is diluted with water, and a cold solution of sulphate of copper
is added. A reddish yellow precipitate falls, which, on being washed and
dried, becomes a beautiful green.
Titanium Green was first prepared by Elsner
in 1846. It is made in the following way: Iserin (titaniferous iron) is
fused in a Hessian crucible with 12 times its weight of sulphate of potash.
When cold, the fused mass is treated with hydrochloric acid, heated to
50° C. and filtered hot; the filtrate is then evaporated until a drop
placed on a glass plate solidifies. It is then allowed to cool, and when
cold a concentrated solution of sal ammoniac is poured over the mass, which
is well stirred and then filtered. The titanic acid which remains behind
is digested at 50° or 70° with dilute hydrochloric acid, and the
acid solution, after the addition of some solution of prussiate of potash,
quickly heated to boiling. A green precipitate falls, which must be washed
with water acidulated with hydrochloric acid, and then dried under 100°
C. Titanium green then forms a beautiful dark green powder.
A Green Color which may be employed in Confectionary.
Infuse for 24 hours 0.32 grammes of saffron
in 7 grammes of distilled water; take 0.26 grammes of carmine of indigo
and infuse in 15.6 grammes of distilled water. On mixing the two liquids
a beautiful green color is obtained, which is harmless. Ten parts will
color 1000 parts of sugar. It may be preserved for a long time by evaporating
the liquid to dryness, or making it into a syrup.
To mix the Mineral Substances in linseed Oil.
Take 1 lb. of the genuine mineral green, prepared
and well powdered, 1 lb. of the precipitate of copper, 1 1/2 lbs. of refiners'
blue verditer, 3 lbs. of white lead, dry powdered, 3 oz. of sugar of lead
powdered fine. Mix the whole of these ingredients in linseed oil, and grind
them in a levigating mill, passing it through until quite fine; it will
thereby produce a bright mineral pea-green paint, preserve a blue tint,
and keep any length of time in any climate without injury, by putting oil
or water over it.
To use this color for house or ship painting,
take 1 lb. of the green color paint, with 1 gill of pale boiled oil, mix
them well together, and this will produce a strong peagreen paint: the
tint may be varied at pleasure by adding a further quantity of white lead
ground in linseed oil. This color will stand the weather and resist salt
water; it may also be used for flatting rooms, by adding 3 lbs. of white
lead ground in half linseed oil and half turpentine, to 1 lb. of the green,
then to be mixed up in turpentine spirits, fit for use. It may also be
used for painting Venetian window blinds, by adding to 1 lb. of the green
paint 10 oz. of white lead, ground in turpentine, then to be mixed up in
turpentine varnish for use. In all the aforsaid preparations it will retain
a blue tint, which is very desirable. When used for blinds, a small quantity
of Dutch pink may be put to the white lead if the color is required of
a yellow cast.
To Imitate
Flesh-color.
Mix a little white and yellow together, then
add a little more red than yellow. These form an excellent imitation of
the complexion.
A White
for Painters, which may be Preserved Forever.
Put into a pan 3 qts. of linseed oil, with
an equal quantity of brandy and 4 qts. of the best double-distilled vinegar,
3 doz. of whole new-laid eggs, 4 lbs. of mutton suet, chopped small; cover
all with a lead plate and lute it well, lay this pan in the cellar for
3 weeks, then take skilfully the white off, and dry it. The dose of this
composition is 6 oz. of white to 1 of bismuth.
To Clean Pictures.
Take the picture out of the frame, lay a coarse
towel on it for 10 or 14 days; keep continually wetting it until it has
drawn out all the filthiness from the picture, pass some linseed oil, which
has been a long time seasoned in the sun, over it, to purify it, and the
picture will become as lively on the surface as new.
Another Method.
Put into 2 qts. of the oldest lye 1/4 lb. of
Genoa soap, rasped very fine, with about a pint of spirit of wine, and
boil all together; then strain it through a cloth, and let it cool. With
a brush dipped in the composition rub the picture all over, and let it
dry; repeat this process and let it dry again, then dip a little cotton
in oil of nut, and pass it over its surface. When perfectly dry, rub it
well over with a warm cloth, and it will appear of a beautiful freshness.
To Restore Discolored White.
In paintings, where the white has become blackened
by sulphuretted hydrogen, the application of Thenard's oxygenated water
will instantly restore it. Probably a solution of permanganate of potassa
would have the same effect. (See CONDY'S SOLUTION).
To Restore
Paintings.
Prof. Pettenkoffer has shown that the change
which takes place in old paintings, is the discontinuance of molecular
cohesion, which, beginning on the surface in small fissures, penetrates
to the very foundation. His process is to expose the picture in a tight
box to the vapor of alcohol, ether benzine, turpentine, or other similar
solvent. The process has been successfully tried in several instances.
Compound for Receiving the Colors used in Encaustic
Painting.
Dissolve 9 oz. of gum arabic in 1 pt. of water,
add 14 oz. of finely powdered mastic and 10 oz. of white wax, cut in small
pieces, and whilst hot, add by degrees 2 pts. of cold spring-water; then
strain the composition.
Another Method.
Mix 24 oz. of mastic with gum-water, leaving
out the wax, and when sufficiently beaten and dissolved over the fire,
add by degrees 1 1/2 pts. of cold water, and strain.
Or, dissolve 9 oz. of gum arabic in 1 1/2 pts.
of water, then add 1 lb. of white wax. Boil them over a slow fire, pour
them into a cold vessel, and beat them well together. When this is mixed
with the colors, it will require more water than the others. This is used
in painting, the colors being mixed with these compositions as with oil,
adding water if necessary. When the painting is finished, melt some white
wax, and with a hard brush varnish the painting, and, when cold, rub it
to make it entirely smooth.
Grecian
Method of Painting on Wax.
Take 1 oz. of white wax and 1 oz. of gum mastic,
in drops, made into powder; put the wax into a glazed pan over a slow fire,
and when melted add the mastic, then stir the same until they are both
incorporated. Next throw the paste into water, and when hard take it out,
wipe it dry, and beat it in a mortar; when dry pound it in a linen cloth
till it is reduced to a fine powder. Make some strong gum-water, and when
painting take a little of the powder, some color, and mix them all with
the gum-water. Light colors require but a small quantity of the powder,
but more must be put in proportion to the darkness of the colors, and to
black there should be almost as much of the powder as of color.
Having mixed the colors, paint with water,
as is practised in painting with water colors, a ground on the wood being
first painted of some proper color, prepared as described for the picture.
When the painting is quite dry, with a hard brush, passing it one way,
varnish it with white wax, which is melted over a slow fire till the picture
is varnished. Take care the wax does not boil. Afterwards hold the picture
before a fire near enough to melt the wax, but not to run, and when the
varnish is entirely cold and hard, rub it gently with a linen cloth. Should
the varnish blister, warm the picture again very slowly, and the bubbles
will subside.
VARNISHES. 1881
Solvents for India-Rubber and Gutta Percha.
1. Benzine. There are two bodies sold as benzine
or benzole: one obtained by distilling coal or coal-tar - the true benzine
- used in making coal tar colors; the other, from petroleum, contains but
little true benzine. They may be used instead of turpentine in mixing paints
and the true benzine for varnishes. Commercial benzine will not generally
do for varnishes; that from petroleum is much the cheaper. Either forms
an excellent solvent for india-rubber.
2. Bisulphide of Carbon is an excellent rubber
solvent; acts in the cold; is made by passing the vapor of sulphur over
red-hot charcoal.
3. Chloroform is very good, but costly.
Turpentine acts slowly, and takes long to dry.
India rubber should always be cut into fine strings or shreds before being
submitted to the action of solvents.
Solvent for Old Paint or Putty.
Caustic soda applied with a broom or brush
made of vegetable matter. It is sold in the shops as concentrated lye.
To
give a Drying Quality to Poppy Oil.
Into 3 lbs. of pure water put 1 oz. of sulphate
of zinc (white vitriol), and mix the whole with 2 lbs. of oil of pinks,
or poppy oil. Expose this mixture, in an earthen vessel capable of standing
the fire, to a degree of heat sufficient to maintain it in a slight state
of ebullition. When one-half or two-thirds of the water has evaporated,
pour the whole into a large glass bottle or jar, and leave it at rest till
the oil becomes clear. Decant the clearest part by means of a glass funnel,
the beak of which is stopped with a piece of cork. When the separation
of the oil from the water is effected, remove the cork stopper, and supply
its place with the forefinger, which must be applied in such a manner as
to suffer the water to escape, and to retain only the oil.
Poppy-oil, when prepared in this manner, becomes,
after some weeks, exceedingly limpid and colorless.
To
give a Drying Quality to Fat Oils.
Take of nut-oil, or linseed-oil, 8 lbs.; white
lead, slightly calcined, yellow acetate of lead (sal saturni), also calcined,
sulphate of zinc (white vitriol), each 1 oz.; vitreous oxide of lead (litharge),
12 oz.; a head of garlic, or a small onion.
When the dry substances are pulverized, mix
them with the garlic and oil, over a fire capable of maintaining the oil
in a slight state of ebullition. Continue it till the oil ceases to throw
up scum, till it assumes a reddish color, and till the head of garlic becomes
brown; a pellicle will then be soon formed on the oil, which indicates
that the operation is completed. Take the vessel from the fire, and the
pellicle, being precipitated by rest, will carry with it all the unctuous
parts which rendered the oil fat. When the oil becomes clear, separate
it from the deposit, and put it into widemouthed bottles, where it will
completely clarify itself in time, and improve in quality.
Another Method.
Take of litharge, 1 1/2 oz.; sulphate of zinc,
3/8 of an oz.: linseed or nut-oil, 16 oz. The operation must be conducted
as in the preceding case.
The choice of the oil is not a matter of indifference.
If it be destined for painting articles exposed to the impression of the
external air, or for delicate painting, nut-oil or poppy-oil. Linseed-oil
is used for coarse painting, and that sheltered from the effects of the
rain and of the sun.
A little negligence in the management of the
fire has often an influence on the color of the oil, to which a drying
quality is communicated; in this case it is not proper for delicate painting.
This inconvenience may be avoided by tying up the drying matters in a small
bag; but the dose of the litharge must then be doubled. The bag must be
suspended by a piece of packthread fastened to a stick, which is made to
rest on the edges of the vessel in such a manner as to keep the bag at
the distance of an inch from the bottom of the vessel. A pellicle will
be formed as in the first operation, but it will be slower in making its
appearance.
Another. - A drying quality may be communicated
to oil by treating, in a heat capable of maintaining a slight ebullition,
linseed or nut-oil, to each pound of which is added 3 oz. litharge, reduced
to fine powder.
The preparation of floor-cloths, and all paintings
of large figures or ornaments, in which argillaceous colors, such as yellow
and red boles, Dutch pink, etc. are employed, require this kind of preparation,
that the dessication may not be too slow; but painting for which metallic
oxides are used, such as preparations of lead, copper, etc., require only
the doses before indicated, because these oxides contain a great deal of
oxygen, and the oil, by their contact, acquires more of a drying quality.
Another. - Take of nut-oil, 2 lbs.; common
water, 3 do.; sulphate of zinc, 2 oz.
Mix these matters, and subject them to a slight
ebullition, till little water remains. Decant the oil, which will pass
over with a small quantity of water, and separate the latter by means of
a funnel. The oil remains nebulous for some time; after which it becomes
clear, and seems to be very little colored.
Another. - Take of nut-oil, or linseed-oil,
6 lbs.; common water, 4 lbs.; sulphate of zinc, 1 oz.; garlic, 1 head.
Mix these matters in a large iron or copper
pan; then place them over the fire, and maintain the mixture in a state
of ebullition during the whole day. Boiling water must from time to time
be added, to make up for the loss of that by evaporation. The garlic will
assume a brown appearance. Take the pan from the fire, and having suffered
a deposit to be formed, decant the oil, which will clarify itself in the
vessel. By this process the drying oil is rendered somewhat more colored.
It is reserved for delicate colors.
Preparation
of a Drying Oil for Zinc Paint.
In order to avoid the use of oxide of lead
in making drying oil for zinc paint, oxide of manganese has been proposed
as a substitute. The process to be adopted is as follows:
The manganese is broken into pieces about the
size of peas, dried, and the powder separated by means of a sieve. The
fragments are then to be introduced into a bag made of iron-wire gauze.
This is hung in the oil contained in an iron or copper vessel, and the
whole heated gently for 24 or 36 hours. The oil must not be allowed to
boil, in which case there is great danger of its running over. When the
oil has acquired a reddish color, it is to be poured into an appropriate
vessel to clear.
For 100 parts of oil 10 of oxide of manganese
may be employed, which will serve for several operations when freshly broken
and the dust separated. Experience has shown, that when fresh oxide of
manganese is used it is better to introduce it into the oil upon the second
day. The process likewise occupies a longer time with the fresh oxide.
Very great care is requisite in this operation to prevent accident, and
one of the principle points to be observed is that the oil is not overheated.
If the boiling should render the oil too thick, this may be remedied by
an addition of turpentine after it has thoroughly cooled.
On the Manufacture
of Drying Linseed Oil without Heat.
When linseed-oil is carefully agitated with
vinegar of lead (tribasic acetate of lead), and the mixture allowed to
clear by settling, a copious white, cloudy precipitate forms, containing
oxide of lead, whilst the raw oil is converted into a drying oil of a pale
straw color, forming an excellent varnish, which, when applied in thin
layers, dries perfectly in 24 hours. It contains from 4 to 5 per cent.
of oxide of lead in solution. The following proportions appear to be the
most advantageous for its preparation:
In a bottle containing 4 1/2 pts. of rain-water,
18 oz. of neutral acetate of lead are placed, and when the solution is
complete, 18 oz. of litharge in a very fine powder are added; the whole
is then allowed to stand in a moderately warm place, frequently agitating
it to assist the solution of the litharge. This solution may be considered
as complete when no more small scales are apparent. The deposit of a shining
white color (sexbasic acetate of lead may be separated by filtration. This
conversion of the neutral acetate of lead into vinegar of lead, by means
of litharge and water, is effected in about a quarter of an hour, if the
mixture be heated to ehullition. When heat is not applied, the process
will usually take 3 or 4 days. The solution of vinegar of lead, or tribasic
acetate of lead, thus formed, is sufficient for the preparation of 22 lbs.
of drying oil. For this purpose the solution is diluted with an equal volume
of rain-water, and to it is gradually added, with constant agitation, 22
lbs. of oil, with which 18 oz. of litharge have previously been mixed.
When the points of contact between the lead
solution and the oil have been frequently renewed by agitation of the mixture
3 or 4 times a day, and the mixture allowed to settle in a warm place,
the limpid straw-colored oil rises to the surface, leaving a copious white
deposit. The watery solution, rendered clear by filtration, contains intact
all the acetate of lead at first employed, and may be used in the next
operation, after the addition to it as before, of 18 oz. of litharge.
By filtration through paper or cotton, the
oil may be obtained as limpid as water, and by exposure to the light of
the sun it may also be bleached.
Should a drying oil be required absolutely
free from lead, it may be obtained by the addition of dilute sulphuric
acid to the above, when, on being allowed to stand, a deposit of sulphate
of lead will take place, and the clear oil may be obtained free from all
trace of lead.
Resinous
Drying Oil.
Take 10 lbs. of drying nut-oil, if the paint
is destined for external articles, or 10 lbs. of drying linseedoil if for
internal; resin, 3 lbs.; turpentine, 6 oz.
Cause the resin to dissolve the oil by means
of a gentle heat. When dissolved and incorporated with the oil, add the
turpentine; leave the varnish at rest, by which means it will often deposit
portions of resin and other impurities; and then preserve it in wide-mouthed
bottles. It must be used fresh; when suffered to grow old it abandons some
of its resin. If this resinous oil assumes too much consistence, dilute
it with a little essence, if intended for articles sheltered from the sun,
or with oil of poppies.
Fat Copal
Varnish.
Take picked copal, 16 oz.; prepared linseed
oil, or oil of poppies, 8 oz.; essence of turpentine, 16 oz.
Liquefy the copal in a matrass over a common
fire, and then add the linseed oil, or oil of poppies, in a state of ebullition;
when these matters are incorporated, take the matrass from the fire, stir
the matter till the greatest heat is subsided, and then add the essence
of turpentine warm. Strain the whole, while still warm, through a piece
of linen, and put the varnish into a wide-mouthed bottle. Time contributes
towards its clarification, and in this manner it acquires a better quality.
Varnish for Watch Cases in Imitation of Tortoiseshell.
Take copal of an amber color, 6 oz.; Venice
turpentine, 1 1/2 oz.; prepared linseed-oil, 24 oz.; essence of turpentine,
6 oz.
It is customary to place the turpentine over
the copal, reduced to small fragments, in the bottom of an earthen or metal
vessel, or in a matrass exposed to such a heat as to liquefy the copal;
but it is more advantageous to liquefy the latter alone, to add the oil
in a state of ebullition, then the turpentine liquefied, and in the last
place the essence. If the varnish is too thick, some essence may be added.
The latter liquor is a regulator for the consistence in the hands of an
artist.
Gold-colored
Copal Varnish.
Take copal in powder, 1 oz.; essential oil
of lavender, 2 oz.; essence of turpentine, 6 oz.
Put the essential oil of lavender into a matrass
of a proper size, placed on a sand-bath heated gently. Add to the oil while
very warm, and at several times, the copal powder, and stir the mixture
with a stick of white wood rounded at the end. When the copal has entirely
disappeared, add at three different times the essence almost in a state
of ebullition, and keep continually stirring the mixture. When the solution
is completed, the result will be a varnish of a gold-color, exceedingly
durable and brilliant.
Another Method.
To obtain this varnish colorless, it will be
proper to rectify the essence of the shops, which is often highly colored,
and to give it the necessary density by exposure to the sun in bottles
closed with cork stoppers, leaving an interval of some inches between the
stopper and the surface of the liquid. A few months are thus sufficient
to communicate to it the required qualities. Besides, essence of the shops
is rarely possessed of that state of consistence without having at the
same time a strong amber color.
The varnish resulting from the solution of
copal in oil of turpentine, brought to such a state as to produce the maximum
of solution, is exceedingly durable and brilliant. It resists the shock
of hard bodies much better than the enamel of toys, which often becomes
scratched and whitened by the impression of repeated friction; it is susceptible
also of a fine polish. It is applied with the greatest success to philosophical
instruments, and the paintings with which vessels and other utensils of
metal are decorated.
Camphorated
Copal Varnish.
This varnish is destined for articles which
require durability, pliableness, and transparency.
Take of pulverized copal, 2 oz.; essential
oil of lavender, 6 oz.; camphor, 1/8 oz.; essence of turpentine, a sufficient
quantity, according to the consistence required to be given to the varnish.
Put into a phial of thin glass, or into a small
matrass, the essential oil of lavender and the camphor, and place the mixture
on a moderately open fir |